|Chārī! Watashi no arata kazoku!!|
|Guardian Angels Of The Stars episode 31|
"Charlie! My New Family!!"
|Air date||January 27, 2015|
|Opening||Love-Colored Rainbow Stars|
|Ending||Rainbow Staff Roll|
|Directed by||Yousei A. Sina|
|Written by||Yousei A. Sina|
- Akahane Ruby/Guardian Angel Crimson
- Yuuki Topaz/Guardian Angel Saffron
- Tachibana Amber/Guardian Angel Sienna
- Midorikusa Emerald/Guardian Angel Cyan
- Aomizu Sapphire/Guardian Angel Azure
- Shirosora Diamond/Guardian Angel Whitney
- Momozaki Rubellit/Guardian Angel Heather
- Itou Amethyst/Guardian Angel Lavender
- Nobumoto Quartz
- Aihara Shizuki
- Itou Haruna (flashback only)
- Itou Asuka (flashback only)
- Itou Ayumu
- It was revealed that the Tsubasa Public Middle School starts a bit later than the other schools.
- Aihara Shizuki, Amethyst's classmate made her debut.
- It was revealed that Amethyst and her sister have always wanted a dog.
- It was shown that Amethyst's father seems to have something against animals.
- It was said that Murasakiiro Asuka loved wolves.
- Charlie seems to feel when an enemy is around, like when he started barking at Ruriri.
- Heather and Lavender learned that they can help cursed people/animal by fighting and purifying them.
- Amethyst was allowed to keep Charlie.
- Amethst called the dog "Charlie".