|Chārī! Watashi no arata kazoku!!|
|Guardian Angels Of The Stars episode 31|
"Charlie! My New Family!!"
|Air date||January 27, 2015|
|Opening||Love-Colored Rainbow Stars|
|Ending||Rainbow Staff Roll|
|Directed by||Yousei A. Sina|
|Written by||Yousei A. Sina|
- Akabayashi Rubi/Guardian Angel Chimaira
- Yuuki Ririan/Guardian Angel Ampere
- Tachibana Amber/Guardian Angel Aurorae
- Minotori Ema/Guardian Angel Clover
- Aoba Sapphie/Guardian Angel Sicilia
- Amashiro Kiyomi/Guardian Angel Millennia
- Momozaki Rikka/Guardian Angel Papillon
- Itou Ami/Guardian Angel Cavetta
- Nobumoto Rosuke
- Aihara Shizuki
- Itou Haruna (flashback only)
- Itou Asuka (flashback only)
- Itou Ayumu
- It was revealed that the Nishiyama Middle School starts a bit later than the other schools.
- Aihara Shizuki, Ami's classmate made her debut.
- It was revealed that Ami and her sister have always wanted a dog.
- It was shown that Ami's father seems to have something against animals.
- It was said that Itou Asuka loved wolves.
- Charlie seems to feel when an enemy is around, like when he started barking at Ruriri.
- Heather and Lavender learned that they can help cursed people/animal by fighting and purifying them.
- Ami was allowed to keep Charlie.